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Chemists made N6. How energetic is it? | Hexanitrogen

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In this educational video, we review a breakthrough in nitrogen chemistry: the preparation of N6! We cover allotropes and uber-sensitive nitrogen compounds, the achievement of making hexanitrogen, and theoretical commentary on potential applications. āž”ļø Check out "Periodic Tales - The Freshman Mole" (+ preview pages) https://total-synthesis.com/freshman-mole/ šŸ‘‰ Follow for updates on random research, mechanism quizzes and interesting news! https://www.instagram.com/totalsynthesis_official/ 00:00 More nitrogens = more fun ... or more problems 00:58 Crazy nitrogen allotropes (including N5+) 04:08 Azidotetrazole 05:45 Periodic Tales: The Freshman Mole 06:10 Cyclic and charged nitrogen allotropes 07:12 Synthesis of N6 (hexanitrogen) 09:14 Detection of N6 11:30 Energy computations for N6 decomposition 14:31 First paper on theoretical performance: Energy 17:57 Rocket propellant 21:23 Other propellant application 22:44 Second paper: Polymeric nitrogen enters the chat 24:17 Is N6 the most powerful energetic material? 24:52 Energy storage and N10 ?!? 25:46 Thank you for watching! Key references: - Preparation of a neutral nitrogen allotrope hexanitrogen C2h-N6 | Nature 2025, 642, 356 - N5+: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material | Angew. Chem. Int. Ed. 1999, 38, 2004 (page number of citation on screen incorrect!) The Preparation of Fluorodiazonium Hexafluoroarsenate (N2F+AsF-) from cis-Difluorodiazine | JACS 1965, 87, 1889 - A series of energetic metal pentazolate hydrates | Nature 2017, 549, 78 - Stabilization of hexazine rings in potassium polynitride at high pressure | Nature Chemistry 2022, 14, 794 - Theoretical Evaluation of the Energetic Properties of Chain-Like Hexanitrogen | Propellants, Explosives, Pyrotechnics 2025, e70045 (early view) - A Comment on the Computed Performance of Hexanitrogen C2h-N6 | Propellants, Explosives, Pyrotechnics 2025, 50, 6 (e70065) - The video I mentioned: https://www.youtube.com/watch?v=EKJQ-6OakgM Recommended organic chemistry books: - Winter; Organic Chemistry I For Dummies (start here if you are absolutely friggin clueless) | https://amzn.to/4fmF97q - Clayden, Greeves, Warren; Organic Chemistry (basic organic chemistry knowledge) | https://amzn.to/4ul57ft - Wyatt, Warren; Organic Synthesis: The Disconnection Approach (excellent introduction to retrosynthesis) | https://amzn.to/4fmF97q | https://amzn.to/3Q529xn - Grossmann; The Art of Writing Reasonable Organic Reaction Mechanisms (building intuition for intermediate and advanced reaction mechanisms) | https://amzn.to/4dOiIXA - Nicolaou; Classics in Total Synthesis 1-4 (simply legendary series) | https://amzn.to/4o986pz | https://amzn.to/3ROsRLp | https://amzn.to/3S4vCYV | https://amzn.to/4dPI9YL - Nicolaou; Molecules That Changed the World (the world's most important molecules and their impact on everyday life) | https://amzn.to/4odZwWW - Carreira, Kvaerno; Classics in Stereoselective Synthesis (compilation of the groundbreaking methods of stereoselective synthesis and application to synthesis of stereochemically complex structures) | https://amzn.to/4dZk9kH - Anslyn; Modern Physical Organic Chemistry (almost anything you will need for (organic) physical chemistry) | https://amzn.to/4gwOZUL - Kurti, Czako; Strategic Applications of Named Reactions in Organic Synthesis (encyclopedia of reactions and common conditions) | https://amzn.to/43cbzKH

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